Researchers split water into hydrogen, oxygen using light, nanoparticles

Researchers split water into hydrogen, oxygen using light, nanoparticles

Researchers from the University of Houston have found a catalyst that can quickly generate hydrogen from water using sunlight, potentially creating a clean and renewable source of energy.

Their research, published online Sunday in Nature Nanotechnology, involved the use of cobalt oxide nanoparticles to split water into hydrogen and oxygen.

Jiming Bao, lead author of the paper and an assistant professor in the Department of Electrical and Computer Engineering at UH, said the research discovered a new photocatalyst and demonstrated the potential of nanotechnology in engineering a material's property, although more work remains to be done.

Bao said photocatalytic water-splitting experiments have been tried since the 1970s, but this was the first to use cobalt oxide and the first to use neutral water under visible light at a high energy conversion efficiency without co-catalysts or sacrificial chemicals. The project involved researchers from UH, along with those from Sam Houston State University, the Chinese Academy of Sciences, Texas State University, Carl Zeiss Microscopy LLC, and Sichuan University.

Researchers prepared the nanoparticles in two ways, using femtosecond laser ablation and through mechanical ball milling. Despite some differences, Bao said both worked equally well.

Different sources of light were used, ranging from a laser to white light simulating the solar spectrum. He said he would expect the reaction to work equally well using natural sunlight.

Once the nanoparticles are added and light applied, the water separates into hydrogen and oxygen almost immediately, producing twice as much hydrogen as oxygen, as expected from the 2:1 hydrogen to oxygen ratio in H2O water molecules, Bao said.

The experiment has potential as a source of renewable fuel, but at a solar-to-hydrogen efficiency rate of around 5 percent, the conversion rate is still too low to be commercially viable. Bao suggested a more feasible efficiency rate would be about 10 percent, meaning that 10 percent of the incident solar energy will be converted to hydrogen chemical energy by the process.

Other issues remain to be resolved, as well, including reducing costs and extending the lifespan of cobalt oxide nanoparticles, which the researchers found became deactivated after about an hour of reaction.

"It degrades too quickly," said Bao, who also has appointments in materials engineering and the Department of Chemistry.

The work, supported by the Welch Foundation, will lead to future research, he said, including the question of why cobalt oxide nanoparticles have such a short lifespan, and questions involving chemical and electronic properties of the material.

University of Houston (2013, December 15). Researchers split water into hydrogen, oxygen using light, nanoparticles. ScienceDaily. Retrieved December 16, 2013, from http://www.sciencedaily.com­/releases/2013/12/131215160904.htm?utm_source=feedburner&utm_medium=feed&utm_campaign=Feed%3A+sciencedaily%2Ftop_news%2Ftop_science+%28ScienceDaily%3A+Top+News+--+Top+Science%29

Hydrogen cars could be headed to showroom near you

Cars that run on hydrogen and exhaust only water vapor are emerging to challenge electric vehicles as the world's transportation of the future.

At auto shows on two continents Wednesday, three automakers were unveiling hydrogen fuel cell vehicles to be delivered to the general public as early as spring of next year.

Korea's Hyundai Motor Co. will be the first to the mass market in the U.S. with a hydrogen-powered Tucson small SUV for lease next spring. Details were to come later Wednesday at the Los Angeles Auto Show. Honda also revealed plans in Los Angeles for a car due out in 2015. Earlier, at the Tokyo Motor Show, Toyota promised a mass-produced fuel cell car by 2015 in Japan and 2016 in the U.S.

Hydrogen cars are appealing because unlike electric vehicles, they have the range of a typical gasoline car and can be refueled quickly. Experts say the industry also has overcome safety and reliability concerns that have hindered distribution in the past.

But hydrogen cars still have a glaring downside—refueling stations are scarce, and costly to build. Critics say the cars are still a long way from mass production.

Consumers can expect costs in line with some luxury models. In Tokyo, Toyota promised a price of 5 million yen ($50,000) to 10 million yen ($100,000), and as close to the lower figure as possible. That's comparable to its Lexus sedans, but a range that makes the once space-age experiment with fuel cells more credible.

Even as battery-powered and hybrid-electric cars took on conventional gasoline models in the past decade, automakers continued research into hydrogen fuel cells, said Paul Mutolo, director of external partnerships for the Cornell University Energy Materials Center. Manufacturers now are limited only by costs and the lack of filling stations, he said.

Hydrogen cars, Mutolo said, have an advantage over battery-powered electric cars because drivers don't have to worry about running out of electricity and having to wait hours for recharging. "It's very similar to the kind of behavior that drivers have come to expect from their gasoline cars," he said.

Hydrogen fuel cells use a complex chemical process to separate electrons and protons in hydrogen gas molecules. The electrons move toward a positive pole, and the movement creates electricity. That powers a car's electric motor, which turns the wheels. "You're literally ripping the electrons from inside the molecule, generating electricity," Mutolo said.

Since the hydrogen isn't burned, there's no pollution. Instead, oxygen also is pumped into the system, and when it meets the hydrogen ions and electrons, that creates water and heat. The only byproduct is water. A fuel cell produces only about one volt of electricity, so many are stacked to create enough juice.

Hydrogen costs as little as $3 for an amount needed to power a car the same distance as a gallon of gasoline, Mutolo said.

Hyundai's plan includes leasing the hydrogen SUVs starting in the Los Angeles area, where most of the state's nine refueling stations are located. California lawmakers have allocated $100 million to build 100 more.

Mutolo estimates it will take at least 10 years for stations to spread nationwide.

Manufacturers likely will lose money on hydrogen cars at first, but costs will decrease as precious metals are reduced in the fuel cells, he said.

Toyota said its new fuel cell vehicle will be for ordinary customers, not just officials and celebrities. The car will go on sale in Japan in 2015 and within a year later in Europe and U.S.

Toyota's fuel cell car is on display as a "concept" model called FCV at the Tokyo show, where alternative fuel is grabbing the spotlight. The FCV looks ready to hit the streets, similar to the Prius gas-electric hybrid.

Honda, which has leased about two-dozen fuel cell cars since 2005, took the wraps off a futuristic-looking FCEV concept vehicle in Los Angeles. The concept vehicle shows the style of a 300-mile range fuel cell car that will be marketed in the U.S. and Japan in 2015 and in Europe after that. Honda wouldn't say if it will be offered for lease or purchase.

All major automakers, including General Motors Co. and Daimler, have been working on fuel cells for decades. But the prospect of reaching showrooms was not very real until recently.

Skeptics say hydrogen-fueling stations are more expensive than electric car charging stations, partly because electricity is almost everywhere and new and safe ways for producing, storing and transferring hydrogen will be needed.

Carlos Ghosn, chief executive of Nissan Motor Co., which has bet heavily on electric vehicles for its future, is one vocal skeptic.

"Having a prototype is easy. The challenge is mass-marketing," he told reporters. He said he did not see a mass-market fuel cell as viable before 2020.

Read more at: http://phys.org/news/2013-11-hydrogen-cars-showroom.html#jCp

How Nanotechnology Can Change Life

Lowering the power consumption of CNT-based CMOS devices to subnanowatt

Researchers have demonstrated a new carbon nanotube (CNT)-based logic device that consumes just 0.1 nanowatts (nW) in its static ON and OFF states, representing the lowest reported value by 3 orders of magnitude for CNT-based CMOS logic devices. The device could serve as a building block for large-area, ultralow-power CNT logic circuits that can be used to realize a variety of nanoelectronics applications.

The researchers, Michael L. Geier, et al., at Northwestern University in Evanston, Illinois, and the University of Minnesota in Minneapolis, have published their paper on the subnanowatt CNT logic in a recent issue of Nano Letters.

'As the researchers explain, one of the biggest advantages of CMOS architecture is that it has intrinsically low power consumption. This benefit arises from the fact that, unlike other logic architectures, one of the two types of transistors (p-type or n-type) is turned off under steady state conditions in each logic gate in CMOS devices.

In order to fully take advantage of this potential for extremely low power consumption, the p-type and n-type transistors need to have precisely tuned and well-separated threshold voltages, which are the voltage levels that determine whether the device is ON or OFF. So far, this issue of the threshold voltages has not been addressed, and the researchers here identified it as the key challenge limiting the realization of highly integrated CNT-based CMOS electronics.

In their study, the researchers used a metal gate structure to achieve symmetric and clearly separated threshold voltages for p-type and n-type CNT transistors, resulting in the ultralow power consumption. In the static states, in which the device is either ON or OFF, power consumption is less than 0.1 nW. At the midpoint of the transfer state, when both p-type and n-type transistors are simultaneously in the ON state, the voltage reaches its peak at 10 nW.'

By connecting multiple CNT transistors in various configurations, the researchers demonstrated inverter, NAND and NOR logic gates. In the future, these gates can be integrated into complex circuits, where they can provide subnanowatt static power consumption along with the other advantages of CNTs, such as solution processability and flexibility.

More information: Michael L. Geier, et al. "Subnanowatt Carbon Nanotube Complementary Logic Enabled by Threshold Voltage Control." Nano Letters. DOI: 10.1021/nl402478p

Read more at: http://phys.org/news/2013-09-carbon-nanotube-logic-device-subnanowatt.html#jCp

Creating electricity with caged atoms

Clathrates are crystals consisting of tiny cages in which single atoms can be enclosed. These atoms significantly alter the material properties of the crystal. By trapping cerium atoms in a clathrate, scientists at the Vienna University of Technology have created a material which has extremely strong thermoelectric properties. It can be used to turn waste heat into electricity.

A lot of energy is wasted when machines turn hot, unnecessarily heating up their environment. Some of this thermal energy could be harvested using thermoelectric materials; they create electric current when they are used to bridge hot and cold objects. At the Vienna University of Technology (TU Vienna), a new and considerably more efficient class of thermoelectric materials can now be produced. It is the material's very special crystal structure that does the trick, in connection with an astonishing new physical effect; in countless tiny cages within the crystal, cerium atoms are enclosed. These trapped magnetic atoms are constantly rattling the bars of their cage, and this rattling seems to be responsible for the material's exceptionally favourable properties.

Cerium Cages from the Mirror Oven

"Clathrates" is the technical term for crystals, in which host atoms are enclosed in cage-like spaces. "These clathrates show remarkable thermal properties", says Professor Silke Bühler-Paschen (TU Vienna). The exact behaviour of the material depends on the interaction between the trapped atoms and the cage surrounding them. "We came up with the idea to trap cerium atoms, because their magnetic properties promised particularly interesting kinds of interaction", explains Bühler-Paschen.

For a long time, this task seemed impossible. All earlier attempts to incorporate magnetic atoms such as the rare-earth metal cerium into the clathrate structures failed. With the help of a sophisticated crystal growth technique in a mirror oven, Professor Andrey Prokofiev (TU Vienna) has now succeeded in creating clathrates made of barium, silicon and gold, encapsulating single cerium atoms.

Electricity from Temperature Differences

The thermoelectric properties of the novel material have been tested. Thermoelectrics work when they connect something hot with something cold: "The thermal motion of the electrons in the material depends on the temperature", explains Bühler-Paschen. "On the hot side, there is more thermal motion than on the cold side, so the electrons diffuse towards the colder region. Therefore, a voltage is created between the two sides of the thermoelectric material."

Experiments show that the cerium atoms increase the material's thermopower by 50%, so a much higher voltage can be obtained. Furthermore, the thermal conductivity of clathrates is very low. This is also important, because otherwise the temperatures on either side would equilibrate, and no voltage would remain.

The World's Hottest Kondo Effect

"The reason for these remarkably good material properties seem to lie in a special kind of electron-electron correlation – the so-called Kondo effect", Silke Bühler-Paschen believes. The electrons of the cerium atom are quantum mechanically linked to the atoms of the crystal. Actually, the Kondo effect is known from low temperature physics, close to absolute zero temperature. But surprisingly, these quantum mechanical correlations also play an important role in the novel clathrate materials, even at a temperature of hundreds of degrees Celcius.

"The rattling of the trapped cerium atoms becomes stronger as the temperature increases", says Bühler-Paschen. "This rattling stabilizes the Kondo effect at high temperatures. We are observing the world's hottest Kondo effect."

More Research for Better and Cheaper Clathrates

The research team at TU Vienna will now try to achieve this effect also with different kinds of clathrates. In order to make the material commercially more attractive, the expensive gold could possibly be substituted by other metals, such as copper. Instead of cerium, a cheaper mixture of several rare-earth elements could be used. There are high hopes that such designer clathrates can be technologically applied in the future, to turn industrial waste heat into valuable electrical energy.

Read more at: http://phys.org/news/2013-09-electricity-caged-atoms.html#jCp

More information: Thermopower enhancement by encapsulating cerium in clathrate cages, DOI: 10.1038/nmat3756

Graphene could yield cheaper optical chips

Optoelectronic devices built from graphene could be much simpler in design than those made from other materials. If a method for efficiently depositing layers of graphene—a major area of research in materials science—can be found, it could ultimately lead to optoelectronic chips that are simpler and cheaper to manufacture.

"Another advantage, besides the possibility of making device fabrication simpler, is that the high mobility and ultrahigh carrier-saturation velocity of electrons in graphene makes for very fast detectors and modulators," says Dirk Englund, the Jamieson Career Development Assistant Professor of Electrical Engineering and Computer Science at MIT, who led the new research.

Graphene is also responsive to a wider range of light frequencies than the materials typically used in photodetectors, so graphene-based optoelectronic chips could conceivably use a broader-band optical signal, enabling them to move data more efficiently. "A two-micron photon just flies straight through a germanium photodetector," Englund says, "but it is absorbed and leads to measurable current—as we actually show in the paper—in graphene."

Read more at: http://phys.org/news/2013-09-graphene-yield-cheaper-optical-chips.html

More information: http://www.nature.com/nphoton/journal/vaop/ncurrent/full/nphoton.2013.253.html

Smartphone as a 'Microscope' to detect a single virus and nanoparticles

With the emerging of cutting edge technology of smartphone as Samsung Galaxy, Iphone etc, your smartphone now can see what the naked eye cannot: A single virus and bits of material less than one-thousandth of the width of a human hair.

Aydogan Ozcan, a professor of electrical engineering and bioengineering at the UCLA Henry Samueli School of Engineering and Applied Science, and his team have created a portable smartphone attachment that can be used to perform sophisticated field testing to detect viruses and bacteria without the need for bulky and expensive microscopes and lab equipment. The device weighs less than half a pound.

"This cellphone-based imaging platform could be used for specific and sensitive detection of sub-wavelength objects, including bacteria and viruses and therefore could enable the practice of nanotechnology and biomedical testing in field settings and even in remote and resource-limited environments," Ozcan said. "These results also constitute the first time that single nanoparticles and viruses have been detected using a cellphone-based, field-portable imaging system."

The new research, published on Sept. 9 in the American Chemical Society's journal ACS Nano, comes on the heels of Ozcan's other recent inventions, including a cellphone camera-enabled sensor for allergens in food products and a smart phone attachment that can conduct common kidney tests.

Capturing clear images of objects as tiny as a single virus or a nanoparticle is difficult because the optical signal strength and contrast are very low for objects that are smaller than the wavelength of light.

In the ACS Nano paper, Ozcan details a fluorescent microscope device fabricated by a 3-D printer that contains a color filter, an external lens and a laser diode. The diode illuminates fluid or solid samples at a steep angle of roughly 75 degrees. This oblique illumination avoids detection of scattered light that would otherwise interfere with the intended fluorescent image.

Using this device, which attaches directly to the camera module on a smartphone, Ozcan's team was able to detect single human cytomegalovirus (HCMV) particles. HCMV is a common virus that can cause birth defects such as deafness and brain damage and can hasten the death of adults who have received organ implants, who are infected with the HIV virus or whose immune systems otherwise have been weakened. A single HCMV particle measures about 150-300 nanometers; a human hair is roughly 100,000 nanometers thick.

In a separate experiment, Ozcan's team also detected nanoparticles -- specially marked fluorescent beads made of polystyrene -- as small as 90-100 nanometers.

To verify these results, researchers in Ozcan's lab used other imaging devices, including a scanning electron microscope and a photon-counting confocal microscope. These experiments confirmed the findings made using the new cellphone-based imaging device.

Ozcan is the principal investigator on the research. The first author of ACS Nano the paper is Qingshan Wei, a postdoctoral researcher in Ozcan's lab and at UCLA's California NanoSystems Institute (CNSI), where Ozcan is associate director. Other co-authors include Hangfei Qi and Ting-Ting Wu of the UCLA Department of Molecular and Medical Pharmacology; Wei Luo, Derek Tseng, Zhe Wan and Zoltan Gorocs of the UCLA Electrical Engineering Department; So Jung Ki of the UCLA Department of Chemistry and Biochemistry; Laurent Bentolila of CNSI and the UCLA Department of Chemistry and Biochemistry; and Ren Sun of the UCLA Department of Molecular and Medical Pharmacology and CNSI.

More information: pubs.acs.org/doi/pdfplus/10.1021/nn4037706

Journal reference: ACS Nano  

Provided by University of California, Los Angeles

Read more at: http://phys.org/news/2013-09-smartphone-microscope-virus-nanoparticles.html#jCp